| By using a confocal microprobe Raman spectroscopy in conjunction with a unique electrochemical surface pretreatment procedure for platinum (Pt) electrodes, we are able to extend the detailed surface Raman studies, for the first time, to the adsorption behavior at bare Pt electrodes in a wide potential region. The surface Raman spectra of pyridine, halide ions (Cl- and Br-), redox couple (Fe(CN)63-/4-), have been obtained in the present study. [View the Article] |